Dog (n.) Old English docga, a late, rare word, used in at least one Middle English source in reference to a powerful breed of canine. The word forced out Old English hund (the general Germanic and Indo-European word; see canine) by 16c. and subsequently was picked up in many continental languages (French dogue (16c.), Danish dogge, German Dogge (16c.)), but the origin remains one of the great mysteries of English etymology."

Source : Online Etymology Dictionary

Note: The Online Etymology Dictionary maintains a free-access list of the origins of thousands of English words, a significant proportion of which are unknown